It's almost the same, you just have to change to use the CONCAT() function instead of the + operator :
Code:
UPDATE tb_Company
SET CompanyIndustry = CONCAT(UCASE(LEFT(CompanyIndustry, 1)),
SUBSTRING(CompanyIndustry, 2));
This would turn hello to Hello, wOrLd to WOrLd, BLABLA to BLABLA, etc. If you want to upper-case the first letter and lower-case the other, you just have to use LCASE function :
Code:
UPDATE tb_Company
SET CompanyIndustry = CONCAT(UCASE(LEFT(CompanyIndustry, 1)),
LCASE(SUBSTRING(CompanyIndustry, 2)));
Note that UPPER and UCASE do the same thing.